Glycosciences.DB structure entry #278:

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 2D Structure
b-D-Galp-(1-4)+ a-L-Fucp-(1-6)+ | | b-D-GlcpNAc-(1-2)-a-D-Manp-(1-6)+ b-D-GlcpNAc-(1-4)-Asn | | | a-L-Fucp-(1-3)+ b-D-Manp-(1-4)-b-D-GlcpNAc-(1-4)+ | a-D-Neup5Ac-(2-6)-b-D-Galp-(1-4)-b-D-GlcpNAc-(1-2)-a-D-Manp-(1-3)+
 SNFG-style Graphics
  3D Structure Model
  Corresponding entries: 1
 Motifs: 3
 General Structure Data
 Composition
  NMR Proton Chemical Shift Info

MHz 500
Temperature 300
Solvent D2O
Note a)Signals stemming from the main component(s) with respect to the heterogeneity of the peptide moiety. Also main components NAc = 2.016 ppm and CH3 = 1.210 ppm.
Residue Linkage Proton PPM JFrom JTo Hz Note
b-D-GlcpNAc  4  H1  5.102      0  a
b-D-GlcpNAc  4  NAC  2.006      0  a
a-L-Fucp  6,4  H1  4.877      0  
a-L-Fucp  6,4  H5  4.125      0  
a-L-Fucp  6,4  CH3  1.206      0  a
b-D-GlcpNAc  4,4  H1  4.682      0  a
b-D-GlcpNAc  4,4  NAC  2.094      0  
b-D-Manp  4,4,4  H1  4.771      0  
b-D-Manp  4,4,4  H2  4.256      0  
a-D-Manp  6,4,4,4  H1  4.910      0  
a-D-Manp  6,4,4,4  H2  4.112      0  
b-D-GlcpNAc  2,6,4,4,4  H1  4.605      0  
b-D-GlcpNAc  2,6,4,4,4  NAC  2.042      0  
b-D-Galp  4,2,6,4,4,4  H1  4.447      0  
a-L-Fucp  3,2,6,4,4,4  H1  5.123      0  
a-L-Fucp  3,2,6,4,4,4  H5  4.829      0  
a-L-Fucp  3,2,6,4,4,4  CH3  1.179      0  
a-D-Manp  3,4,4,4  H1  5.134      0  
a-D-Manp  3,4,4,4  H2  4.191      0  
b-D-GlcpNAc  2,3,4,4,4  H1  4.605      0  
b-D-GlcpNAc  2,3,4,4,4  NAC  2.069      0  
b-D-Galp  4,2,3,4,4,4  H1  4.445      0  
a-D-Neup5Ac  6,4,2,3,4,4,4  H3A  1.720      0  
a-D-Neup5Ac  6,4,2,3,4,4,4  H3E  2.667      0  
a-D-Neup5Ac  6,4,2,3,4,4,4  NAC  2.030      0  
  Literature references: 13
 Taxonomy: 1
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