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Glycosciences.DB structure entry #277:

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Format: CarbBank LINUCS


       b-D-Galp-(1-4)+
                     |
                b-D-GlcpNAc-(1-6)+
                     |           |
       a-L-Fucp-(1-3)+      a-D-Manp-(1-6)+
                                 |        |
 b-D-Galp-(1-4)-b-D-GlcpNAc-(1-2)+        |
                                     b-D-Manp-(1-4)-b-D-GlcpNAc-(1-4)-b-D-GlcpNAc-(1-4)-Asn-(1-2)-Gly-(1-2)-Thr
 b-D-Galp-(1-4)-b-D-GlcpNAc-(1-4)+        |
                                 |        |
                            a-D-Manp-(1-3)+
                                 |
 b-D-Galp-(1-4)-b-D-GlcpNAc-(1-2)+

SNFG-style Graphics

3D Structure Model

download coordinates

Corresponding entries: 1

1 - 1 of 1 entries with matching glycan part

Structure entry #22990:

b-D-Galp-(1-4)+ | b-D-GlcpNAc-(1-6)+ | | a-L-Fucp-(1-3)+ a-D-Manp-(1-6)+ | | b-D-Galp-(1-4)-b-D-GlcpNAc-(1-2)+ | b-D-Manp-(1-4)-b-D-GlcpNAc-(1-4)-b-D-GlcpNAc b-D-Galp-(1-4)-b-D-GlcpNAc-(1-4)+ | | | a-D-Manp-(1-3)+ | b-D-Galp-(1-4)-b-D-GlcpNAc-(1-2)+

no NMR spectra

no literature references

no Ref

no GlycoMaps

Taxons

Lewis X (Show) (Search Database)
N-glycan core (Show) (Search Database)
Lactosamine (Show) (Search Database)

General Structure Data

Chemical Formula:	C₁₀₆H₁₇₆N₁₀O₇₄		#C	#H	#O	#N
Molec. Weight:	2773		106	176	74	10
# Atoms:	366
# Residues:	17
# Heavy Atoms:	190

Superclasses:

Hex
Hex	7
dHex	1
HexNAc	6

Residues:

Residue	Count
A-D-MANP	2
A-L-FUCP	1
ASN	1
B-D-GALP	4
B-D-GLCPNAC	6
B-D-MANP	1
GLY	1
THR	1

NMR Proton Chemical Shift Info

MHz	500
Temperature	300
Solvent	D2O
Note	a)Tentative assignment. b)Assignments are interchanged in the article.
Residue	Linkage	Proton	PPM	JFrom	JTo	Hz	Note
b-D-GlcpNAc	4	H1	5.067			0
b-D-GlcpNAc	4	NAC	2.006			0
b-D-GlcpNAc	4,4	H1	4.611			0
b-D-GlcpNAc	4,4	NAC	2.076			0
b-D-Manp	4,4,4	H1	4.758			0
b-D-Manp	4,4,4	H2	4.209			0
a-D-Manp	6,4,4,4	H1	4.866			0
a-D-Manp	6,4,4,4	H2	4.092			0
b-D-GlcpNAc	6,6,4,4,4	H1	4.563			0	a
b-D-GlcpNAc	6,6,4,4,4	NAC	2.029			0
b-D-Galp	4,6,6,4,4,4	H1	4.473			0
a-L-Fucp	3,6,6,4,4,4	H1	5.112			0
a-L-Fucp	3,6,6,4,4,4	H5	4.832			0
a-L-Fucp	3,6,6,4,4,4	CH3	1.177			0
b-D-GlcpNAc	2,6,4,4,4	H1	4.594			0
b-D-GlcpNAc	2,6,4,4,4	NAC	2.040			0
b-D-Galp	4,2,6,4,4,4	H1	4.470			0
a-D-Manp	3,4,4,4	H1	5.124			0
a-D-Manp	3,4,4,4	H2	4.222			0
a-D-Manp	3,4,4,4	H3	4.052			0
b-D-GlcpNAc	4,3,4,4,4	H1	4.545			0
b-D-GlcpNAc	4,3,4,4,4	NAC	2.077			0
b-D-Galp	4,4,3,4,4,4	H1	4.468			0	b
b-D-GlcpNAc	2,3,4,4,4	H1	4.570			0
b-D-GlcpNAc	2,3,4,4,4	NAC	2.052			0
b-D-Galp	4,2,3,4,4,4	H1	4.462			0	b

Literature references: 5

1 - 5 of 5 literature references

Reference #7724

Bierhuizen MFA; Edzes HT; Schiphorst WECM; van den Eijnden DH; van Dijk W

Effect of .alpha.(2-6)-linked sialic acid and .alpha.(1-3)-linked fucose on the interaction of N-linked glycopeptides and related oligosaccharides with immobilized Phaseolus vulgaris leukoagglutinating lectin (L-PHA)

Published 1988 in Glycoconj J, 5: 85-97

Reference contains 12 structures

Reference #9643

Joziasse DH; Schiphorst WECM; van den Eijnden DH; van Kuik JA; van Halbeek H; Vliegenthart JFG

Branch specificity of bovine colostrum CMP-sialic acid: Gal.beta.1-4GlcNAc-R .alpha.2-6-sialyltransferase. Sialylation of bi-, tri-, and tetraantennary oligosaccharides and glycopeptides of the N-acetyllactosamine type

Published 1987 in J Biol Chem, 262: 2025-2033

Reference contains 39 structures

Vliegenthart JFG; Dorland L; van Halbeek H

High-resolution, 1H-nuclear magnetic resonance spectroscopy as a tool in the structural analysis of carbohydrates related to glycoproteins

Published 1983 in Adv Carbohydr Chem Biochem, 41: 209-374

Reference contains 72 structures

Reference #9371

van Halbeek H; Dorland L; Vliegenthart JFG; Montreuil J; Fournet B; Schmid K

Characterization of the microheterogeneity in glycoproteins by 500-MHz 1H-NMR spectroscopy of glycopeptide preparations. Application to a monofucosylated tetra-antennary glycopeptide fraction from human plasma .alpha.1-acid glycoprotein

Published 1981 in J Biol Chem, 256: 5588-5590

Reference contains 3 structures

Reference #13639

Vliegenthart JFG; van Halbeek H; Dorland L

The applicability of 500-MHz high-resolution 1H-NMR spectroscopy for the structure determination of carbohydrates derived from glycoproteins

Published 1981 in Pure Appl Chem, 53: 45-77

Reference contains 26 structures

NCBI Taxonomy ID	Scientific Name
9606	Homo sapiens

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