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Glycosciences.DB structure entry #238:
b-D-Galp-(1-4)-b-D-GlcpNAc-(1-6)+
|
a-D-Manp-(1-6)+
| |
b-D-Galp-(1-4)-b-D-GlcpNAc-(1-2)+ |
b-D-Manp-(1-4)-D-GlcNAc
b-D-Galp-(1-4)-b-D-GlcpNAc-(1-4)+ |
| |
a-D-Manp-(1-3)+
|
b-D-Galp-(1-4)-b-D-GlcpNAc-(1-2)+
[][D-GLCNAC]{[(4+1)][B-D-MANP]{[(3+1)][A-D-MANP]{[(2+1)][B-D-GLCPNAC]{[(4+1)][B-D-GALP]{}}[(4+1)][B-D-GLCPNAC]{[(4+1)][B-D-GALP]{}}}[(6+1)][A-D-MANP]{[(2+1)][B-D-GLCPNAC]{[(4+1)][B-D-GALP]{}}[(6+1)][B-D-GLCPNAC]{[(4+1)][B-D-GALP]{}}}}}
RES
1b:x-dglc-HEX-x:x
2s:n-acetyl
3b:b-dman-HEX-1:5
4b:a-dman-HEX-1:5
5b:b-dglc-HEX-1:5
6s:n-acetyl
7b:b-dgal-HEX-1:5
8b:b-dglc-HEX-1:5
9s:n-acetyl
10b:b-dgal-HEX-1:5
11b:a-dman-HEX-1:5
12b:b-dglc-HEX-1:5
13s:n-acetyl
14b:b-dgal-HEX-1:5
15b:b-dglc-HEX-1:5
16s:n-acetyl
17b:b-dgal-HEX-1:5
LIN
1:1d(2+1)2n
2:1o(4+1)3d
3:3o(3+1)4d
4:4o(2+1)5d
5:5d(2+1)6n
6:5o(4+1)7d
7:4o(4+1)8d
8:8d(2+1)9n
9:8o(4+1)10d
10:3o(6+1)11d
11:11o(2+1)12d
12:12d(2+1)13n
13:12o(4+1)14d
14:11o(6+1)15d
15:15d(2+1)16n
16:15o(4+1)17d
<?xml version="1.0" encoding="UTF-8"?>
<sugar version="1.0">
<residues>
<basetype id="1" anomer="x" superclass="hex" ringStart="-1" ringEnd="-1" name="x-dglc-HEX-x:x">
<stemtype id="1" type="dglc" />
</basetype>
<substituent id="2" name="n-acetyl" />
<basetype id="3" anomer="b" superclass="hex" ringStart="1" ringEnd="5" name="b-dman-HEX-1:5">
<stemtype id="1" type="dman" />
</basetype>
<basetype id="4" anomer="a" superclass="hex" ringStart="1" ringEnd="5" name="a-dman-HEX-1:5">
<stemtype id="1" type="dman" />
</basetype>
<basetype id="5" anomer="b" superclass="hex" ringStart="1" ringEnd="5" name="b-dglc-HEX-1:5">
<stemtype id="1" type="dglc" />
</basetype>
<substituent id="6" name="n-acetyl" />
<basetype id="7" anomer="b" superclass="hex" ringStart="1" ringEnd="5" name="b-dgal-HEX-1:5">
<stemtype id="1" type="dgal" />
</basetype>
<basetype id="8" anomer="b" superclass="hex" ringStart="1" ringEnd="5" name="b-dglc-HEX-1:5">
<stemtype id="1" type="dglc" />
</basetype>
<substituent id="9" name="n-acetyl" />
<basetype id="10" anomer="b" superclass="hex" ringStart="1" ringEnd="5" name="b-dgal-HEX-1:5">
<stemtype id="1" type="dgal" />
</basetype>
<basetype id="11" anomer="a" superclass="hex" ringStart="1" ringEnd="5" name="a-dman-HEX-1:5">
<stemtype id="1" type="dman" />
</basetype>
<basetype id="12" anomer="b" superclass="hex" ringStart="1" ringEnd="5" name="b-dglc-HEX-1:5">
<stemtype id="1" type="dglc" />
</basetype>
<substituent id="13" name="n-acetyl" />
<basetype id="14" anomer="b" superclass="hex" ringStart="1" ringEnd="5" name="b-dgal-HEX-1:5">
<stemtype id="1" type="dgal" />
</basetype>
<basetype id="15" anomer="b" superclass="hex" ringStart="1" ringEnd="5" name="b-dglc-HEX-1:5">
<stemtype id="1" type="dglc" />
</basetype>
<substituent id="16" name="n-acetyl" />
<basetype id="17" anomer="b" superclass="hex" ringStart="1" ringEnd="5" name="b-dgal-HEX-1:5">
<stemtype id="1" type="dgal" />
</basetype>
</residues>
<linkages>
<connection id="1" parent="1" child="2">
<linkage id="1" parentType="d" childType="n">
<parent pos="2" />
<child pos="1" />
</linkage>
</connection>
<connection id="2" parent="1" child="3">
<linkage id="2" parentType="o" childType="d">
<parent pos="4" />
<child pos="1" />
</linkage>
</connection>
<connection id="3" parent="3" child="4">
<linkage id="3" parentType="o" childType="d">
<parent pos="3" />
<child pos="1" />
</linkage>
</connection>
<connection id="4" parent="4" child="5">
<linkage id="4" parentType="o" childType="d">
<parent pos="2" />
<child pos="1" />
</linkage>
</connection>
<connection id="5" parent="5" child="6">
<linkage id="5" parentType="d" childType="n">
<parent pos="2" />
<child pos="1" />
</linkage>
</connection>
<connection id="6" parent="5" child="7">
<linkage id="6" parentType="o" childType="d">
<parent pos="4" />
<child pos="1" />
</linkage>
</connection>
<connection id="7" parent="4" child="8">
<linkage id="7" parentType="o" childType="d">
<parent pos="4" />
<child pos="1" />
</linkage>
</connection>
<connection id="8" parent="8" child="9">
<linkage id="8" parentType="d" childType="n">
<parent pos="2" />
<child pos="1" />
</linkage>
</connection>
<connection id="9" parent="8" child="10">
<linkage id="9" parentType="o" childType="d">
<parent pos="4" />
<child pos="1" />
</linkage>
</connection>
<connection id="10" parent="3" child="11">
<linkage id="10" parentType="o" childType="d">
<parent pos="6" />
<child pos="1" />
</linkage>
</connection>
<connection id="11" parent="11" child="12">
<linkage id="11" parentType="o" childType="d">
<parent pos="2" />
<child pos="1" />
</linkage>
</connection>
<connection id="12" parent="12" child="13">
<linkage id="12" parentType="d" childType="n">
<parent pos="2" />
<child pos="1" />
</linkage>
</connection>
<connection id="13" parent="12" child="14">
<linkage id="13" parentType="o" childType="d">
<parent pos="4" />
<child pos="1" />
</linkage>
</connection>
<connection id="14" parent="11" child="15">
<linkage id="14" parentType="o" childType="d">
<parent pos="6" />
<child pos="1" />
</linkage>
</connection>
<connection id="15" parent="15" child="16">
<linkage id="15" parentType="d" childType="n">
<parent pos="2" />
<child pos="1" />
</linkage>
</connection>
<connection id="16" parent="15" child="17">
<linkage id="16" parentType="o" childType="d">
<parent pos="4" />
<child pos="1" />
</linkage>
</connection>
</linkages>
</sugar>
3D Structure Model1 - 1 of 1 entries with matching glycan part
Structure entry #11771:
b-D-Galp-(1-4)-b-D-GlcpNAc-(1-6)+
|
a-D-Manp-(1-6/3)+
| |
b-D-Galp-(1-4)-b-D-GlcpNAc-(1-2)+ |
b-D-Manp-(1-4)-D-GlcNAc
b-D-Galp-(1-4)-b-D-GlcpNAc-(1-4)+ |
| |
a-D-Manp-(1-3/6)+
|
b-D-Galp-(1-4)-b-D-GlcpNAc-(1-2)+
 |
 |
 |
 : 2 |
 |
Taxons: 1 |
- Lactosamine (Show) (Search Database)
| Chemical Formula: | C82H137N5O61 | #C | #H | #O | #N | |
| Molec. Weight: | 2168 | 82 | 137 | 61 | 5 | |
| # Atoms: | 285 | |||||
| # Residues: | 12 | |||||
| # Heavy Atoms: | 148 | |||||
Superclasses:
|
Residues:
|
||||||||||||||||||
NMR Proton Chemical Shift Info| MHz | 500 | ||||||
| Temperature | 300 | ||||||
| Solvent | D2O | ||||||
| Note | a)Assignments are interchanged in the article. See: J. Biol. Chem (1987) 262: 2025-2033 | ||||||
| Residue | Linkage | Proton | PPM | JFrom | JTo | Hz | Note |
| D-GlcNAc | H1A | 5.205 | 0 | ||||
| D-GlcNAc | H1B | 4.719 | 0 | ||||
| D-GlcNAc | NACA | 2.059 | 0 | ||||
| D-GlcNAc | NACB | 2.056 | 0 | ||||
| b-D-Manp | 4 | H1(A) | 4.768 | 0 | |||
| b-D-Manp | 4 | H1(B) | 4.761 | 0 | |||
| b-D-Manp | 4 | H2(A) | 4.214 | 0 | |||
| b-D-Manp | 4 | H2(B) | 4.203 | 0 | |||
| a-D-Manp | 6,4 | H1 | 4.870 | 0 | |||
| a-D-Manp | 6,4 | H2 | 4.099 | 0 | |||
| b-D-GlcpNAc | 6,6,4 | H1 | 4.554 | 0 | |||
| b-D-GlcpNAc | 6,6,4 | NAC(A) | 2.038 | 0 | |||
| b-D-GlcpNAc | 6,6,4 | NAC(B) | 2.040 | 0 | |||
| b-D-Galp | 4,6,6,4 | H1 | 4.480 | 0 | |||
| b-D-GlcpNAc | 2,6,4 | H1 | 4.592 | 0 | |||
| b-D-GlcpNAc | 2,6,4 | NAC(A) | 2.041 | 0 | |||
| b-D-GlcpNAc | 2,6,4 | NAC(B) | 2.045 | 0 | |||
| b-D-Galp | 4,2,6,4 | H1(A) | 4.469 | 0 | |||
| b-D-Galp | 4,2,6,4 | H1(B) | 4.471 | 0 | |||
| a-D-Manp | 3,4 | H1(A) | 5.131 | 0 | |||
| a-D-Manp | 3,4 | H1(B) | 5.129 | 0 | |||
| a-D-Manp | 3,4 | H2(A) | 4.228 | 0 | |||
| a-D-Manp | 3,4 | H2(B) | 4.224 | 0 | |||
| a-D-Manp | 3,4 | H3(A) | 4.056 | 0 | |||
| a-D-Manp | 3,4 | H3(B) | 4.053 | 0 | |||
| b-D-GlcpNAc | 4,3,4 | H1 | 4.547 | 0 | |||
| b-D-GlcpNAc | 4,3,4 | NAC | 2.079 | 0 | |||
| b-D-Galp | 4,4,3,4 | H1 | 4.469 | 0 | a | ||
| b-D-GlcpNAc | 2,3,4 | H1 | 4.572 | 0 | |||
| b-D-GlcpNAc | 2,3,4 | NAC | 2.054 | 0 | |||
| b-D-Galp | 4,2,3,4 | H1 | 4.464 | 0 | a | ||
Literature references: 131 - 5 of 13 literature references
Reference #5146
Helin J; Maaheimo H; Seppo A; Keane A; Renkonen O
Stepwise transfer of .alpha.-D-Galp-(1-3)-.beta.-D-Galp-(1-4)-.beta.-D-GlcpNAc sequences to 3-OH and 6-OH of distal galactose residues in bi-, tri-, and tetra-antennary asialo-glycans of N-linked complex type
Published 1995 in Carbohydr Res, 266: 191-209
Reference contains 16 structures
Reference #1825
Feizi T; Solomon JC; Yuen CT; Jeng KCG; Frigeri LG; Hsu DK; Liu FT
The adhesive specificity of the soluble human lectin, IgE-binding protein, toward lipid-linked oligosaccharides. Presence of the blood group A, B, B-like, and H monosaccharides confers a binding activity to tetrasaccharide (lacto-N-tetraose and lacto-N-n
Published 1994 in Biochemistry, 33: 6342-6349
Reference contains 1 structure
Reference #7836
Nemansky M; van den Eijnden DH
Enzymatic characterization of CMP-NeuAc:Gal.beta.1-4GlcNAc-R .alpha.(2-3)-sialyltransferase from human placenta
Published 1993 in Glycoconj J, 10: 99-108
Reference contains 20 structures
Reference #7806
Ayouba A; Debray H; Rouge P
Fine sugar specificity of the Butea frondosa seed lectin
Published 1992 in Glycoconj J, 9: 141-147
Reference contains 26 structures
Reference #1356
Jackson P
The use of polyacrylamide-gel electrophoresis for the high-resolution separation of reducing saccharides labeled with the fluorophore 8-aminonaphthalene-1,3,6-trisulfonic acid. Detection of picomolar quantities by an imaging system based on a cooled char
Published 1990 in Biochem J, 270: 705-713
Reference contains 1 structure
| NCBI Taxonomy ID | Scientific Name |
| 9606 | Homo sapiens |
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