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Glycosciences.DB structure entry #1667:
a-L-Fucp-(1-2)-b-D-Galp-(1-4)+
|
b-D-GlcpNAc-(1-6)+
| |
a-L-Fucp-(1-3)+ D-GalNAc-ol
|
a-L-Fucp-(1-2)-b-D-Galp-(1-3)+
[][D-GALNAC-OL]{[(3+1)][B-D-GALP]{[(2+1)][A-L-FUCP]{}}[(6+1)][B-D-GLCPNAC]{[(3+1)][A-L-FUCP]{}[(4+1)][B-D-GALP]{[(2+1)][A-L-FUCP]{}}}}
RES
1b:o-dgal-HEX-0:0|1:aldi
2s:n-acetyl
3b:b-dgal-HEX-1:5
4b:a-lgal-HEX-1:5|6:d
5b:b-dglc-HEX-1:5
6s:n-acetyl
7b:a-lgal-HEX-1:5|6:d
8b:b-dgal-HEX-1:5
9b:a-lgal-HEX-1:5|6:d
LIN
1:1d(2+1)2n
2:1o(3+1)3d
3:3o(2+1)4d
4:1o(6+1)5d
5:5d(2+1)6n
6:5o(3+1)7d
7:5o(4+1)8d
8:8o(2+1)9d
<?xml version="1.0" encoding="UTF-8"?>
<sugar version="1.0">
<residues>
<basetype id="1" anomer="o" superclass="hex" ringStart="0" ringEnd="0" name="o-dgal-HEX-0:0|1:aldi">
<stemtype id="1" type="dgal" />
<modification type="aldi" pos_one="1" />
</basetype>
<substituent id="2" name="n-acetyl" />
<basetype id="3" anomer="b" superclass="hex" ringStart="1" ringEnd="5" name="b-dgal-HEX-1:5">
<stemtype id="1" type="dgal" />
</basetype>
<basetype id="4" anomer="a" superclass="hex" ringStart="1" ringEnd="5" name="a-lgal-HEX-1:5|6:d">
<stemtype id="1" type="lgal" />
<modification type="d" pos_one="6" />
</basetype>
<basetype id="5" anomer="b" superclass="hex" ringStart="1" ringEnd="5" name="b-dglc-HEX-1:5">
<stemtype id="1" type="dglc" />
</basetype>
<substituent id="6" name="n-acetyl" />
<basetype id="7" anomer="a" superclass="hex" ringStart="1" ringEnd="5" name="a-lgal-HEX-1:5|6:d">
<stemtype id="1" type="lgal" />
<modification type="d" pos_one="6" />
</basetype>
<basetype id="8" anomer="b" superclass="hex" ringStart="1" ringEnd="5" name="b-dgal-HEX-1:5">
<stemtype id="1" type="dgal" />
</basetype>
<basetype id="9" anomer="a" superclass="hex" ringStart="1" ringEnd="5" name="a-lgal-HEX-1:5|6:d">
<stemtype id="1" type="lgal" />
<modification type="d" pos_one="6" />
</basetype>
</residues>
<linkages>
<connection id="1" parent="1" child="2">
<linkage id="1" parentType="d" childType="n">
<parent pos="2" />
<child pos="1" />
</linkage>
</connection>
<connection id="2" parent="1" child="3">
<linkage id="2" parentType="o" childType="d">
<parent pos="3" />
<child pos="1" />
</linkage>
</connection>
<connection id="3" parent="3" child="4">
<linkage id="3" parentType="o" childType="d">
<parent pos="2" />
<child pos="1" />
</linkage>
</connection>
<connection id="4" parent="1" child="5">
<linkage id="4" parentType="o" childType="d">
<parent pos="6" />
<child pos="1" />
</linkage>
</connection>
<connection id="5" parent="5" child="6">
<linkage id="5" parentType="d" childType="n">
<parent pos="2" />
<child pos="1" />
</linkage>
</connection>
<connection id="6" parent="5" child="7">
<linkage id="6" parentType="o" childType="d">
<parent pos="3" />
<child pos="1" />
</linkage>
</connection>
<connection id="7" parent="5" child="8">
<linkage id="7" parentType="o" childType="d">
<parent pos="4" />
<child pos="1" />
</linkage>
</connection>
<connection id="8" parent="8" child="9">
<linkage id="8" parentType="o" childType="d">
<parent pos="2" />
<child pos="1" />
</linkage>
</connection>
</linkages>
</sugar>
3D Structure Model- Lewis Y (Show) (Search Database)
- Blood Group H Antigen (Show) (Search Database)
| Chemical Formula: | ||
| Molec. Weight: | ||
| # Atoms: | ||
| # Residues: | 7 | |
| # Heavy Atoms: | ||
Superclasses:
|
Residues:
|
||||||||||||||||||
NMR Proton Chemical Shift Info| MHz | 500 | ||||||
| Temperature | 300 | ||||||
| Solvent | D2O | ||||||
| Residue | Linkage | Proton | PPM | JFrom | JTo | Hz | Note |
| D-GalNAc-ol | H2 | 4.401 | 0 | ||||
| D-GalNAc-ol | H3 | 4.081 | 0 | ||||
| D-GalNAc-ol | H4 | 3.486 | 0 | ||||
| D-GalNAc-ol | H5 | 4.249 | 0 | ||||
| D-GalNAc-ol | NAC | 2.054 | 0 | ||||
| b-D-GlcpNAc | 6 | H1 | 4.563 | 0 | |||
| b-D-GlcpNAc | 6 | H6 | 4.030 | 0 | |||
| b-D-GlcpNAc | 6 | NAC | 2.049 | 0 | |||
| b-D-Galp | 4,6 | H1 | 4.497 | 0 | |||
| a-L-Fucp | 2,4,6 | H1 | 5.279 | 0 | |||
| a-L-Fucp | 2,4,6 | H5 | 4.242 | 0 | |||
| a-L-Fucp | 2,4,6 | CH3 | 1.271 | 0 | |||
| a-L-Fucp | 3,6 | H1 | 5.100 | 0 | |||
| a-L-Fucp | 3,6 | H5 | 4.871 | 0 | |||
| a-L-Fucp | 3,6 | CH3 | 1.235 | 0 | |||
| b-D-Galp | 3 | H1 | 4.570 | 0 | |||
| b-D-Galp | 3 | H4 | 3.921 | 0 | |||
| a-L-Fucp | 2,3 | H1 | 5.217 | 0 | |||
| a-L-Fucp | 2,3 | H5 | 4.273 | 0 | |||
| a-L-Fucp | 2,3 | CH3 | 1.244 | 0 | |||
Literature references: 51 - 5 of 5 literature references
Reference #4653
Klein A; Carnoy C; Lo-Guidice JM; Lamblin G; Roussel P
Separation of mucin oligosaccharide-alditols by high performance liquid chromatography on alkylamine-bonded silica columns. Effects of structural parameters
Published 1992 in Carbohydr Res, 236: 9-16
Reference contains 42 structures
Reference #6645
Chai W; Hounsell EF; Cashmore GC; Rosankiewicz JR; Bauer CJ; Feeney J; Feizi T; Lawson AM
Neutral oligosaccharides of bovine submaxillary mucin. A combined mass spectrometry and 1H-NMR study
Published 1992 in Eur J Biochem, 203: 257-268
Reference contains 18 structures
Reference #461
Reddy GP; Bush CA
High-performance anion exchange-chromatography of neutral milk oligosaccharides and oligosaccharide alditols derived from mucin glycoproteins
Published 1991 in Anal Biochem, 198: 278-284
Reference contains 26 structures
Reference #6482
Klein A; Lamblin G; Lhermitte M; Roussel P; Breg J; van Halbeek H; Vliegenthart JFG
Primary structure of neutral oligosaccharides derived from respiratory mucus glycoproteins of a patient suffering from bronchiectasis, determined by combination of 500-MHz 1H-NMR spectroscopy and quantitative sugar analysis. 1. Structure of 16 oligosacch
Published 1988 in Eur J Biochem, 171: 631-642
Reference contains 1 structure
Reference #2003
Dua VK; Dube VE; Bush CA
The combination of normal-phase and reverse-phase high-pressure liquid chromatography with NMR for the isolation and characterization of oligosaccharide alditols from ovarian cyst mucins
Published 1984 in Biochim Biophys Acta, 802: 29-40
Reference contains 9 structures
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